High-affinity host–guest chemistry of large-ring cyclodextrins
نویسندگان
چکیده
منابع مشابه
Superstructures with cyclodextrins: Chemistry and applications IV
Cyclodextrins (CDs) are of increasing scientific and commercial interest because they are readily available, harmless and well-defined, forming sophisticated supramolecular structures in aqueous media. More than 2,300 publications and more than 1,200 patents appeared in 2015 in which CDs played a significant role. As exemplified in the following, CD chemistry has developed into a very attractiv...
متن کاملSuperstructures with cyclodextrins: Chemistry and applications
Since their discovery more than 100 years ago, a significant development in CD research has taken place. Right after their discovery, CDs were very expensive due to the fact that only small quantities were available. In addition to this, it was assumed that CDs are toxic to human beings. Meanwhile, things have changed. Now, large quantities of CDs are available at low prices. Additionally, it c...
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Cyclodextrins (CDs) attract much attention for industrial applications and academic research. A few experimental methods for determination of the binding constant between CD and a guest molecule were reviewed critically. A hydrophile–hydrophobe matching model for host–guest docking was proposed for estimation of the binding constant and the solution structure of the complex. Rather detailed sol...
متن کاملElectrospun Fibers of Cyclodextrins and Poly(cyclodextrins).
Cyclodextrins (CDs) can endow electrospun fibers with outstanding performance characteristics that rely on their ability to form inclusion complexes. The inclusion complexes can be blended with electrospinnable polymers or used themselves as main components of electrospun nanofibers. In general, the presence of CDs promotes drug release in aqueous media, but they may also play other roles such ...
متن کاملInorganic crown: the host-guest chemistry of a high nuclearity 'Celtic-ring' isopolyoxotungstate [H12W36O120]12-.
A range of complexes based on the high-nuclearity [W36] isopolyoxotungstate cluster, [H12W36O120]12-, with a triangular topology has been isolated by using the organic cation, protonated triethanolamine. In analogy to an 18-crown-6 crown ether with six oxygen donors on a ring, the cluster can form alkali and alkaline earth metal complexes [M within W36] (M = K+, Rb+, Cs+, NH4+, Sr2+ and Ba2+, 1...
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ژورنال
عنوان ژورنال: Organic & Biomolecular Chemistry
سال: 2016
ISSN: 1477-0520,1477-0539
DOI: 10.1039/c6ob01161f